Effect of mineralogical variations on physico

Scientific Reports volume 13, Article number: 10320 (2023) Cite this article

353 Accesses

Metrics details

The present study aims to explain the geochemical and mineralogical details of the granitic rock types in Gabal EL-Faliq area, South Eastern Desert of Egypt, in relation to geotechnical engineering and their suitability as dimension stones. The objective of the current research was achieved through two steps; the first step involved geological studies such as the petrographic, geochemical, and mineralogical investigations. The second and applicable step involved the geotechnical assessment of the studied rocks by measuring their engineering properties such as physical, mechanical, and thermal expansion properties. The petrographic investigation revealed that the studied granitic rocks are divided into two main classes: (1) gneissose granites (Biotite–Perthite) of medium to fine-grained size and (2) alkali-feldspar granites of coarse to medium-grained size. Mineralogically, the studied rocks are composed mainly of albite, orthoclase and quartz in varying proportions, along with some accessory minerals such as apatite and rutile in addition to some minor quantities of iron-group minerals such as hematite and ilmenite. The engineering properties showed that the maximum water absorption and apparent porosity values are 0.34% and 0.77%, respectively, while the minimum bulk density is 2604.03 kg/m3. The compressive strength ranges from 999.68 to 2469.10 kg/cm2, while the abrasion resistance varies from 29.67 to 54.64 Ha. The increase in albite content led to an increase in water absorption while a decrease in bulk density and compressive strength. The increase in the grain size led to an increase in apparent porosity and a decrease in mechanical properties. A Great variation in the expansion coefficient as well as the length change, occurs under changes in temperature, mineral composition, and physical properties. The increase in heating temperatures caused an insignificant increase in linear thermal expansion with a maximum value of 0.0385% at 100 °C. These results indicated the suitability of the studied granites as dimension stones for use in indoor and outdoor decorative purposes (cladding/paving) under variable temperature conditions.

Dimension stones are any type of natural stones or rock products, excluding all manmade materials that simulate stone, that can be cut to obtain elements having well-determined geometrical shapes or sizes and satisfy the normal requirements of polishing ability, color, texture, and surface finish to be utilized as building and ornamental materials such as building facing, paving stone, curbing, monuments and memorials, and other industrial products1,2,3,4,5. Therefore, the classification of natural stones as dimensional stones is governed by their appearance and dimensions which are the two main criteria. Furthermore, the dimension stones should satisfy the strength, polish-ability and resistance to physical and chemical weathering6.

The igneous, metamorphic, and sedimentary rocks are the three main categories of natural stones based on origin and are widely used all over the world in many applications such as dimension stones due to the great variety of their appearances in addition to their high compactness and durability that enabled them to be used in flooring, cladding, paving, funeral monuments, and statues7. Natural stones are the most widely applied material in ancient heritage constructions such as pyramids, castles, and palaces. The use of dimension stones in traditional constructions is closely related to the distribution of rock outcrops8.

According to (ASTM C119)1, the dimension stones were classified into several groups including granite, limestone, marble, quartz-based (quartzite), and slate groups in addition to other dimension stones such as alabaster and serpentine. However, the two most common groups of natural dimension stones are marble or calcareous material groups and granite or siliceous material groups in addition to other stone types like quartzite and slate3,4. The first group (marble) comprises the whole class of carbonate rocks, composed normally of calcite and dolomite and capable of taking sawing and polishing, outside the limits of the mere lithologic characterization3,9. It is ranging in composition from stones of pure carbonate to that containing very little carbonate that is classed commercially as marble-like (serpentine marble)1. The second common group (granite) comprises, in a commercial definition, the whole set of eruptive or igneous rocks having granular structure and poly-mineral composition, irrespective of the content of quartz3.

The production of dimension stones is increasing rapidly as a result of the massive expansion of building construction projects due to the continuous increase in the population. The worldwide net production of dimension stones reached about one hundred fifty million tons in 2017 by 27 countries10, with a major sharing of about 72% by China, India, Turkey, Iran, and Italy6,11.

Locally, Egypt is distinguished by a wide distribution of different types of natural stones of more than fifty brands that can be utilized as dimension and ornamental stones12,13. Therefore, Egypt occupied the seventh place in the world in the production of dimension stones14 with a production volume of about 5.25 Million tons with 4% global sharing as mentioned in Montani Report 201810.

In Egypt, the granitic intrusions constitute about 60% of the total Neoproterozoic rocks15,16. They are attributed to syn-orogenic calc-alkaline, late- post-orogenic highly fractionated granitoids and post-orogenic alkaline granitic rocks7,17. Furthermore, these intrusions incorporate grey, white, pink, and red granites18. The generation of such granitic rocks was proposed by two possible mechanisms: the first mechanism is magma differentiation (fractional crystallization or assimilation) of mantle-derived basaltic melt, while the second proposed mechanism is partial melting of crustal rocks (mafic-acidic igneous or sedimentary rocks). The granitic rocks attracted the attention of many authors due to their wide exposure and composition, well appearance, and economically hosting of significant rare earth metals such as Nb, Ta, U, Th, Zr, Sn, and W7,19,20,21.

According to (Alzahrani et al. 2022)7, the variation in the mineralogical and chemical composition of the granitic rocks resulted in a variation in their thermal expansion and spectral reflectance behaviors in addition to their physical and mechanical properties. They stated that the low iron oxide granitic rocks have a high spectral reflection in the (VIS-NIR) and (SWIR) spectral regions. Moreover, the granitic rocks of high iron and/or low quartz content revealed a high physical and mechanical performance.

According to (Siegesmund et al. 2018)22, thermal expansion is a physical property, which occurs under the change in all material's temperatures, where most of the materials upon heating and cooling expand and contract; respectively. In thermally sensitive materials, temperature changes cause a pronounced alteration that is well known as physical or mechanical weathering. Though the relatively small extent of thermal expansion with its minor effects on the volume change and bulk density of the rocks, the variations in the characteristics of thermal expansion of different minerals in the assemblage of mineral grains can cause structural damage upon heating the rock. One of the causes of rock deterioration is thermal expansion. This results from that the heat conductivity of granitic rocks is bad, and as thermal action on the rock surface is more intense than in its interior, tensions develop causing the formation of cracks in the outer surface of the rock23.

The thermal studies on granitic rocks collected from the Himalayan regions and the Peninsular shield in India revealed that the mineral composition, grain orientation, crack porosity, rate of heating, and thermal cycling have a great effect on their linear thermal expansion coefficient of granites24.

Plevova et al. (2016)25 applied several thermal (DTA, TG, TMA, αH), mineralogical, and petrographical investigations on six granitic rock samples from three countries. They observed a relative similarity in the thermal expansion values, while a little difference in the shapes of their TMA curves. They attributed such differences to their quartz and feldspar content, feldspar crystallinity and the ratio of anorthite and albite in the granite rocks.

The variations in the thermal expansion coefficients of the individual rock-forming minerals as well as the rock fabric are considered the important parameters that the thermal expansion of a rock is dependent on Ref.22. They investigated the effect of temperature (up to 120 °C) as well as the mineralogical composition on the thermal properties of several granitoid rocks. They observed much higher thermal expansion coefficients in the granitoid rocks rich in quartz compared to that rich in K-feldspar or plagioclase content. However, the contribution of biotite and hornblende minerals modifies the thermal expansion of whole rock.

There are several factors influencing the degree of thermal expansion in rocks such as their mineralogical composition (especially the quartz and calcite content), crystal orientation (structure) in addition to their degree of porosity23. They determined the linear thermal expansion coefficients of some Brazilian granitic rocks commercially used as building facings within a temperature range of 0 to 50 °C and compared these values with the quartz content, apparent porosity, and grain size of the studied rocks. They observed that the increase in quartz content of the granitic rocks led to an increase in their thermal coefficient values. On the other hand, a decrease in thermal coefficient was observed with increasing apparent porosity and grain size.

Mineral constituents, grain size, texture, and degree of alteration of the rocks, are the main factors affecting the engineering properties and durability performance or the rate of degradability of stones26,27,28,29,30,31,32. Hemmati et al. (2020)29 studied the effect of mineralogy and texture of different crystalline igneous rocks on their strength properties and found a relationship between the compressive and tensile strength of the studied igneous rocks and their quartz/feldspar size ratio. The effect of temperature changes on the physical and mechanical properties of dimension stones, especially igneous rocks, is highly obvious due to their wide mineralogical composition that exhibits a variable thermal variation under different temperature degrees33.

Other studies have dealt with the petrographic characteristics of stone aggregates such as alteration degree, mineral composition, and stone texture and their effects on the durability performances of concrete34,35. They found that the final strength of the concrete specimens was affected by mineralogy and microstructure of the coarse aggregates.

Despite the abundance of intrusive igneous rocks in the Gebel El-Faliq area, South Eastern Desert of Egypt with great variations in their colors and types, there are no studies were carried out on the granitic rocks of this area related to their suitability as dimension stones. Moreover, the global climatic changes accompanied by the increase in temperatures may have a great impact on the engineering properties of these rocks. Therefore, the main objective of the current research was directed to evaluate the thermal behavior and some engineering properties of different varieties of the Neoproterozoic granitic rocks located in Gebel El-Faliq area, South Eastern Desert, Egypt, and their suitability as dimension stones for use in the cladding and flooring applications. Moreover, the influence of the mineralogical and chemical compositions of the different granitic rocks on their thermal and engineering properties was also studied. Additionally, the results of engineering properties of the studied granitic rocks were compared to the international standard specifications related to ornamental (dimension) stones. To achieve the above-mentioned objectives, several analyses and investigations were carried out on the collected rock types such as elementary analysis by X-ray fluorescence (XRF), petrographical examination by polarizing light microscope, thermal expansion coefficient by dilatometer, in addition to measuring some engineering properties such as physical properties (apparent porosity, water absorption, and bulk density) and mechanical properties (compressive strength, abrasion resistance) according to the international standard test methods (ASTM).

Egyptian Neoproterozoic rocks are well exposed parallel to the Red Sea (Eastern Desert), South Sinai and Uwainate area, Northern territory of the Arabian Nubian Shield (ANS). ANS represents well juvenile crust, which is formed by arc accretion, followed by crustal thickening and closing of Mozambique Ocean17,36,37,38,39,40,41. Evolution of ANS is involved by large granitic intrusions with a wide diversity in mineralogical and tectonic regime7,17,20. Gebal El Faliq is delineated by Latitude 24° 36' and 24° 37' N and Longitude 34° 28' and 34° 33' E covering ~10 km2 (Fig. 1). It locates in southwestern of Wadi Ghadir-Hafafit, South Eastern Desert, Egypt. Mylonitic, ophiolitic ultramafic rocks, younger granites and post-granitic dikes and pegmatites are the main rocks crop out in the investigated area. Low relief of mylonitic rocks is exposed in the northwestern side of Gabal El Faliq younger granites. Ophiolitic rocks, as they are widely distributed in the Eastern Desert (Central and Southern sides)17,42,43, they cover most of the examined area, which are represented by dunite (or peridotites)44 and mélange rocks45. Gabal El Faliq is represented by younger granitic rocks with elongated sheets along NW-SE trend certainly along Wadi Abu Gherban. They reveal low- to moderate-topographic (664 m above sea level) relief that is represented by monzogranites and alkali feldspar granites45. They are dissected by numerous faults (sinistral-strike slip fault as a major fault), therefore, sheared and gneissose texture are well exposed, particularly along shear zone and fault planes. They are injected by basic dykes and pegmatites with the main NW-SE direction. Some of these pegmatites with variable widths and lengths are enriched with rare metals, such as Zr, Nb, Ta, Th, U and REE44. In addition, they possess xenoliths from the surrounding rocks certainly along their margins. Some alteration features are observed such as hematitization and kaolinization, particularly along shear zone and fault planes.

Geologic map of Gabal El Faliq area (modified after: Mahmoud 201944; Saleh et al. 201445).

According to (Global Carbon Project, 2021), Egypt accounts for only 0.6 percent of annual global carbon dioxide (CO2) emissions, however, it is becoming one of the most heavily affected by extreme weather patterns46. Eid et al.47 analyzed the monthly, seasonal and annual values of temperature over Egypt during the period 1960-2016. They found that the differences between the values of mean temperature in the north and the south of Egypt are measured at 5 °C, 8 °C, 9 °C, and 6 °C in winter, spring, summer, and autumn; respectively. They found that the difference between the values of mean annual temperature in the north and the south of Egypt is about 7.5 °C.

Regarding the total annual precipitation, Nashwan and Shahid48 gives a future look at the changes in precipitation amount and characteristics over Egypt by the end of the century. They revealed an increase in annual precipitation by up to 54% mostly in the north, with a decrease in winter precipitation by 35% Markus et al.49 stated that the most frequently used climate classification map is that of Wladimir Köppen, presented in its latest version 1961 by Rudolf Geiger. It is used to denote different climate regions on Earth based on local vegetation.

For the current research, seven intrusive igneous rocks, of a younger granitic type, were collected from Gabal El-Faliq study area as shown in (Fig. 2). The difference in rock types sampling was based on the hand specimen's variation in color (due to variation in mineral composition) and texture (due to variation in grain size and orientation). Some representative samples were polished for visual illustration as shown in (Fig. 3) Regarding samples preparation, each granitic rock type was divided into three shapes as follows: two cylindrical specimens with dimensions of 20 mm length and 5 mm diameter, six cubic specimens with dimensions of 50 x 50 x 50 mm, and three specimens with dimensions of 50 mm square and 25 mm thickness. The gneissose rock samples were cut perpendicular to their grain orientation.

Photographs showing hand specimens of different types of Gabal El Faliq granitic rocks.

Photographs showing polished surface of selected types of granitic rocks.

The collected granitic rocks of different types were configurated for elementary analysis through grinding and sieving under 74 µm sieve size and then dried in an oven dryer at 105 ± 5 °C overnight for complete dryness. Part of each prepared sample was ignited at 1000 °C for measuring the loss on ignition (L.O.I) % following the standard test method (ASTM E-1621). The major and trace elements of the prepared rock samples were measured at the National Research Center (NRC), using X-Ray Fluorescence (XRF), Axios, PANalytical 2005 with Sequential WD-XRF Spectrometer. Based on the XRF analysis, the normative mineral composition of the studied granitic rocks was calculated using (CIPW normative method) according to (Streckeisen 1976)50.

For identifying the rock-forming minerals, grain texture, and alteration or deformation indices using a polarized light microscope (petrographic analysis), thin sections of the rock types were prepared by cutting into slabs of few millimeters thick using rock cutting machine with a diamond saw, polished using rotary grinding machine and then mounted on a glass slide using Canada Balsam and smoothly grounded using progressively finer abrasive grit until the sample reaching a thin slice of approximately 0.03 mm thick.

The studied granitic rocks were geotechnically evaluated in terms of 1) physical properties such as water absorption, apparent porosity, and bulk density, 2) mechanical properties such as compressive strength and abrasion resistance according to (ASTM C615)51. The samples were cut using a rock-cutting machine into two dimensions as follows: (a) 50 × 50 × 50 mm for measuring water absorption and bulk density according to (ASTM C97)52 and compressive strength according to (ASTM C170)53. (b) 50 × 50 × 25 mm for measuring the abrasion resistance according to (ASTM C241)54. The rock samples were cut to sizes and their physical and mechanical properties were measured in the marble and granite testing lab (MGTL) at National Research Centre (NRC).

The water absorption, apparent density, dry bulk density, and saturated-surface dry bulk density were calculated to the following equations:

The compressive strength is calculated according to the equation:

The cylindrically-shaped rock samples of around 20 mm in length and 5 mm in diameter were used for measuring linear thermal expansion coefficients (α) and length change (thermal strain) (dL/Lo) by stepwise heating at a rate of 5 °C / min up to 1000 °C using a Dilatometer instrument (NETZSCH DIL 402 PC model). The test was carried out in the central lab of the institute at the National Research Centre (NRC).

This article does not contain any studies with human participants or animals performed by any of the authors.

All authors are agreed to be listed as authors in current version of manuscript.

The petrographic examination of Gabal El Faliq granitic rocks was performed using a polarizing microscope to identify their mineralogical constituntes and textural features to revels some significant attributes affected these rocks. Based on the mineralogical composition and the main textural relationship, Gabal El Faliq granitic rocks are divided into two major types: gneissose granites and alkali feldspar granites according to IUGS classification50. The gneissose type (with mainly porphyritic texture and elongated crystals type), includes the rock types F1, F2, and F3, whereas the alkali feldspar type (hypidiomorphic and rarely porphyritic textures), possesses coarse-grained rock type F4 and medium-grained rock types F5, F6, and F7. All samples are investigated as below:

The samples of this type are composed mainly of plagioclase, quartz, potash feldspar and minor subordinate biotite minerals. Plagioclase occurs as phenocrysts crystal mantled by fine-grained quartz and biotite forming porphyritic texture (Fig. 4a). It occurs as medium-grained crystals, reveals extensive alteration saussuritizaion and exhibits lamellar, zoned and Carlsbad twinning. It is poikilitically enclosing fine-grained chlorite. Potash feldspars are represented by perthite and rarely microcline. Perthite reveals a xenomorphic of patchy type that mostly engulfs plagioclase. Quartz range from medium- to fine-grained crystals. It shows clear undulose extension due to deformation processes. Commonly, it occurs as elongated crystals (Fig. 4b). Biotite occurs as fine-grained (shreds), flaky crystals that are partially to completely altered to chlorite. The main textures of this rock type are myrmekitic, and porphyritic textures.

Photomicrographs reveal: (a) Highly saussuritized phenocrysts surrounded by fine-grained quartz and plagioclase (F1); (b) Elongated quartz and perthite crystals as a result of deformation processes (F1); (c) Highly deformed, elongated and fractured perthite phenocrysts surrounded by fin-grained quartz (F2); (d) Phenocrysts of perthite surrounded by fine-grained quartz and perthite forming porphyritic texture (F2); (e) Fine-grained of elongated quartz and feldspar crystals (F3); and (f) Perthite phenocrystals enclosing fine-grained of plagioclase yielding poikiolitic texture (F3).

The samples of this type are medium-grained with pink color in the hand specimen. It consists mainly of potash feldspar, quartz, and minor subordinate plagioclase minerals. Potash feldspars are represented by perthite (with a clear worm-like shape) of flamy type that is mostly fractured and filled by secondary quartz (Fig. 4c). Commonly, it occurs as phenocrysts surrounded by fine-grained quartz forming a porphyritic texture. Microcline is rare and exists as fine-grained crystals (Fig. 4d). Quartz range from fine- to medium crystals with a clear wavy extension due to deformation processes. Plagioclase is rare and mostly occurs as fine-grain. It reveals extensive saussuritizaion. Allanite and zircon are the main accessory minerals. Zircon occurs as euhedral metamect crystals. Allanite occurs as zoned, tabular crystals with brown color.

The samples of this type are composed essentially of plagioclase, quartz, potash feldspar and minor subordinate biotite minerals. Plagioclase occurs as phenocrysts crystal mantled by fine-grained quartz forming porphyritic texture. It occurs as elongated, medium-grained crystals, and exhibits lamellar, Carlsbad and zoned twinning. It is poikilitically enclosing fine-grained quartz. It reveals a turbid surface due to slightly to extensive saussuritizaion. Quartz exist as fine-grained crystals with undulose extension. Commonly, quartz is elongated forming gneissose texture (Fig. 4e). Potash feldspars are represented by perthite and microcline. Perthite exists as phenocrystals that mostly include fine-grained plagioclase (Fig. 4f). They reveal extensive a turbid surface due to kaolinitization processes. Biotite occurs as fine-grained, and elongated flaky crystals. The main textures in this rock are myrmekitic, and porphyritic textures.

In this rock type, K-feldspars, quartz, plagioclase, and muscovite are the main essential minerals. Orthoclase perthite and antiperthite are the main K-feldspar minerals (Fig. 5a and b). Occasionally, it is fractured and filled by iron oxides. Occasionally, antiperthite enclosing fine-grained plagioclase minerals. Quartz exists as medium-to coarse-grained that exhibit both normal and wavy extension. Tabular crystals of plagioclase are partially to completely altered saussurite. Biotite occurs as fine-grained flaky crystals that mostly present as cluster minerals. It is altered to chlorite and stained by iron oxides certainly along its peripheries.

Photomicrographs reveals: (a) Antiperthite phenocrystals enclosing saussuritized plagioclase (F4); (b) Coarse-grained orthoclase perthite (F4); (c) Fractured coarse-grained orthoclase perthite that filled by secondary quartz (F7); (d) Extensive turbid surface of plagioclase crystals (F6); (e) Pyramid- like shape of perthite crystal surrounded by sericite (F6); and (f) Euhedral of skeleton quartz crystal (F5).

It consists mainly of K-feldspar, quartz, and plagioclase, whereas zircon and iron oxide are the main accessory minerals. Orthoclase-perthite and microcline are the main K- feldspar minerals. They reveal a slightly turbid surface as a result of kaolinitizaion processes. Reaction rims between two perthite crystals are observed. Occasionally, orthoclase-perthite occurs as phenocrysts embedded in fine-grained quartz and plagioclase crystals (Fig. 5c). Sometimes occur as a pyramid-like shape mantled by shreds of sericite (Fig. 5e). They are fractured and filled by secondary quartz. Plagioclase occurs as prismatic crystals with clear extensive turbid surface (Fig. 5d). It exhibits pericline and lamellar twinning. Quartz reveals a wavy extension and occurs as anhedral to subhedral skeleton phenocrysts forming porphyritic texture (Fig. 5f). Biotite flaky crystals are partially altered to chlorite. High relief of euhedral zircon crystals occurred. The summary of the petrographic description of the different types of granitic rocks were presented in Table 1.

The petrographic description of the studied granites exhibited deformation effects expressed as fragmentation of quartz and plagioclase crystals. Moreover, the physico-mechanical properties may also be affected by the alteration processes, such as the saussuritization and chlorite formation as well as crystal deformation.

Twenty-one samples of seven plutonic rock types of Gabal El Faliq area were chemically analyzed for major oxides (%) and trace elements (ppm) and listed in Tables 2 and 3. From these tables, it is noticeable that the examined rocks exhibit a wide variation in their chemical compositions.

The geochemical characteristics of Gabal El Faliq granitic intrusion were previously investigated45. This section is concerned with the geochemical composition of variable granitic rocks of Gabal El Faliq area. The major oxides and trace elements of the studied rock types were analyzed using XRF and the results are listed in Tables 2 and 3.

From Table 2, it is noticeable that the studied rocks show a wide variation in their chemical composition. The content of SiO2 varies from 71. 34 to 77.73 % (av. 73.49 %), Al2O3 ranges from 11.85 to 14.66 % (av. 13.79 %), the total Fe2O3T ranges from 1.38 to 3.21 % (av. 2.04 %), and the total alkalis (K2O+Na2O) content ranges from 5.77 to 11.22 % (av. 8.5 %).

Regarding the granitic rock type (F2), it exhibited the highest silica content (av. 76.22), while the lowest alumina content (av. 12.45) relative to other rocks of the area under investigation. However, based on the petrographic examination, this rock type is classified as gneissose granite (due to the outer deformations). Moreover, based on its mineralogical component, this type is relatively fresh (plagioclase reveals saussuritizaion). Therefore, their chemical composition may be ascribed to highly feldspar fractionation.

Variable discrimination diagrams can be used to classify the studied granitic rocks of Gabal El Faliq area. In terms of R1-R2 diagram55, all rock samples (F2, F5, F6, and F7) locate in the alkali-granites field except samples (F1 and F3) and plotted in granite field (Fig. 6a). Further constraints, based on Ab-Or-An ternary diagram50, samples (F1 and F3) lie within syenogranite field, while others occupy alkali-feldspar granite field (Fig. 6b).

Geochemical diagrams of Gabal El Faliq granitic rocks: (a) R1-R2 diagram of (De la Roche et al., 1980)55; (b) Ab-Or-An normative diagram of (Streckeisen, 1976)50; (c) AFM ternary diagram of (Irvine and Baragar, 1971)56 and (d) ACNK vs. ANK binary diagram of (Shand, 1951)57.

It is noticeable that the examined rock samples have a calc‐alkaline affinity (Fig. 6c) according to AFM (Na2O+K2O-Fe2O3T-MgO) diagram56. Further constrains, their calc‐alkaline signature is suggested by their agpaitic index (AI) < 0.87. Moreover, they revealed "peraluminous affinity" as indicated by alumina saturation index (ASI), where A/CNK> 1.1. This is supported by A/CNK- A/NK binary diagram57 (Fig. 6d).

On the other hand, the examined samples of Gabal El Faliq granitic intrusion exhibit a wide variation from samples (F1 and F3) (syenogranites) that are enriched by biotite and plagioclase relative to other samples. It is observed that they are enriched with Sr (av. 159.5 ppm) and Ba (av. 298.5 ppm) relative to the average value (av. 24.44 ppm for Sr, and 109 for Ba) of the other samples (F 2, 4, 5, 6, and 7). Multi-trace elements are normalized to primitive mantle58, (Fig. 7a). They exhibit strong K, Ba, Sr, and Ti negative anomalies, reflecting highly fractional crystallization of feldspars, and titanite minerals. Controversy, they reveal positive Rb, Pb, Zr and Y anomalies.

Geochemical diagrams of Gabal El Faliq granitic rocks: (a) Multi-trace elements normalized to primitive mantle by (Sun and McDonough 1989)56,58; (b) Zr vs. 104Ga/Al binary diagrams by (Whalen et al. 1987)59; (c) Nb + Y vs. Rb binary diagram by (Pearce et al. 1984)60; (d) Discrimination diagram by (Sylvester 1989)61 in which the rocks are > 68 wt. % SiO2; and (e) Source ternary diagram by (Laurent et al. 2014)62.

Its widely known that the granitic rocks are attributed to syn-orogenic (calc-alkaline), late- post-orogenic highly fractionated granitoids (calc-alkaline to alkaline) and post-orogenic (alkaline) granitic rocks7,18. The grey granite rocks represent the older ones and include rocks such as tonalite and granodiorite that are developed in volcanic arc setting, whereas the youngest rocks (alkaline) are commonly attributed to within plate / rift related granites15,16,19,21.

In the current research, the authors would like to link the mineralogical/chemical composition of the examined rocks and their tectonic regime with their geotechnical and engineering aspects. Therefore, by using the geochemical diagrams, all the examined granitic rocks are represented by highly evolved calc-alkaline granitic rocks (formed by fractional crystallization of I-type) of the post-orogenic regime.

The tectonic emplacement of the examined rocks can be manifested by using several geotectonic diagrams. The investigated rocks contain high content of Zr and Ga/Al ratio, reflecting an orogenic (A-type) granites59, with the exception of sample No. F1 that plot has I-type affinity (Fig. 7b). This result is supported by binary diagram60, where all samples plot in A-type field, whereas F1 and F3 samples plot in the field of volcanic arc granites due to less content of Y and Nb elements. In addition, all samples plot within post-collisional granites. In spite of, some of these samples plotted in the sector of A-type granites, have a geochemical characteristic of calc- alkaline granites (Fig. 7c), and highly fractionated calc-alkaline rocks61 (Fig. 7d). This is related to the extensive fractional crystallization of I-type (tonalite) melt62 (Fig. 7e).

Based on the chemical analysis (oxides percentages) of the studied granitic rocks using XRF (X-Ray Fluorescence), the mineral composition of these rocks was calculated using "CIPW classification". Such classification was based upon the reorganizing of the chemical analysis from percentages of oxides into amounts of “standard minerals”50,63 as given in (Table 4). The hypothetical standard mineral composition of the studied granitic rock based upon "CIPW classification" revealed that the predominant mineralogical composition in all studied rocks is detected in the following order "Quartz: SiO2", "Albite: NaAlSi3O8", "Orthoclase: KAlSi3O8", "Anorthite: CaAl2Si2O8" along with some accessory minerals such as "Apatite: Ca5(Cl.F) (PO4)3", "Rutile: TiO2", "Corundum: Al2O3", in addition to iron-mineral group such as "Haematite: Fe2O3", "Ilmenite: FeTiO3".

These minerals were detected in different proportions from rock type to other. It was detected that the quartz content varied from (av. 27.86%) for (F1 rock type) to (av. 38.129%) for (F2 rock type). Regarding the predominant feldspar mineral content, it was detected that the "albite" is the main plagioclase minerals with an average content ranging from (23.83%) for (F2 rock type) to (41.56%) for (F6 rock type). The second predominant feldspar mineral is alkali-feldspar particularly "orthoclase" with an average content ranging from (20.79%) for (F3 rock type) to (32.129%) for (F2 rock type).

The geotechnical assessment of granitic rocks in terms of engineering properties and thermal behavior are the main parameters used to evaluate their suitability as dimension or ornamental stones for the construction and building purposes51. According to ASTM specification, the requirements of granitic rocks for use as dimension stones including (water absorption, density, compressive strength, modulus of rupture, abrasion resistance, and flexural strength) were listed under the term “physical properties”.

In the present study, the engineering properties of the investigated granitic rocks at Gebel El-Faliq area were divided into two groups: (1) the physical properties group including (water absorption and bulk density in addition to apparent porosity); and (2) the mechanical properties group that including (compressive strength, abrasion resistance). These properties were graphically plotted and shown in (Figs. 8 and 9).

Physical properties of Gebel El-Faliq granitic rocks and their relationships with mineralogical composition.

Mechanical properties of Gebel El-Faliq granitic rocks and their relationships with physical properties and mineralogical content.

Figure 8 illustrates the physical properties of the studied granitic rocks, and it was observed that the results of water absorption (Fig. 8a) ranged from 0.06% for (F2-rock type) to 0.34% for (F7-rock type) that were matching with the results of their apparent porosity (Fig. 8b) that ranged from 0.15% to 0.88%, respectively, which confirm the very strong positive relationship between apparent porosity and water absorption. The variation in these properties may be related to the variation in mineralogical composition as shown in (Fig. 8c and d). This figure shows that the water absorption behaves in line with albite content, while in the case of orthoclase, it has an inverse behavior.

The values of water absorption fall within the standard specification limits (< 0.40%)51. The current results were found parallel to the findings obtained by (Alzahrani et al. 20227 and Rashwan et al. 202332) on different types of granites that ranged from 0.14% to 0.52% for water absorption and from 0.36% to 1.36% for apparent porosity. On the contrary, other studies such as (Siegesmund et al. 201822, Török and Török 201564 and Freire-Lista et al. 202265) investigated several types of igneous rocks and recorded high ranges of water absorption and apparent porosity values that ranged from 0.78% to 3.53% and from 0.3% to 6.66%; respectively.

The results of bulk density (dry and wet) of the studied granitic rocks were illustrated (Fig. 8e and f). It was observed from this figure that the values of dry and wet densities ranged from 2604.03 kg/m3 and 2611.72 kg/m3 (F 6—rock type) to 2642.4 kg/m3 and 2645.02 kg/m3 (F 1—rock type); respectively. These results matched in an inverse relationship with the results of the apparent porosity as shown in (Fig. 8g). Although the similarity between apparent porosity values of (F3 and F6—rock types), there is a difference in bulk density between them. Therefore, the variation in the values of rock densities was considered a function of their mineralogical content, where there is an inverse relationship between the albite content of rocks and their bulk density (Fig. 8h), while a positive relationship between both quartz/orthoclase contents of rocks and their bulk density was reported (Fig. 8i). As the albite is the main mineral composition forming the studied granitic rocks than orthoclase, there is an inverse relationship between total feldspar content and the bulk density (Fig. 8j).

The values of bulk density of the present study were looked similar to the findings obtained by (Alzahrani el al. 2022)7 in the range of 2582 to 2644 kg/m3, (Török and Török 2015)64 in the range of (2.58–2.68 g/cm3), (Rashwan et al. 2023)32 in the range of 2590 to 2748 kg/m3, (Dionísio et al. 2021)66 in the range of 2.48–2.63 g/cm3 and (Freire-Lista et al. 2022)65 2461–2649 kg/m3.

Comparing the results of the bulk density with the standard specification relating to granite dimension stone according to (ASTM C615)51, it was observed that all investigated rocks satisfied the requirements (2560 kg/m3 as a minimum limit).

Compressive strength and abrasion resistance are the most important mechanical properties that evaluate the durability and soundness of the rocks intended to be used as dimension stones for building purposes.

The results of compressive strength and abrasion resistance of Gebel El-faliq granitic rocks were graphically illustrated (Fig. 9). It was observed that the values of compressive strength ranged from 98.03 MPa (999.68 kg/cm2) recorded for (F4-rock type) to 242.13 MPa (2469.10 kg/cm2) recorded for (F2-rock type) as shown in (Fig. 9a). The variation in the compressive strength results could be a function of several parameters such as apparent porosity (Fig. 9b), bulk density (Fig. 9c), and feldspar content (Fig. 9d). From these relationships, it was observed that the compressive strength decreases with increasing apparent porosity and plagioclase, it increases with increasing bulk density and alkali feldspar content.

The results of abrasion resistance as shown in (Fig. 9e) ranged from 29.67 Ha (0.462 mm abrasion depth) for (F7-rock type) to 54.64 Ha (0.298 mm abrasion depth) for (F2-rock type). As the porosity of a rock may weaken the cohesion between its grains and consequently lowers its durability, (Fig. 9f) shows a positive relationship between abrasion resistance values (Ha) of the studied rocks and their apparent porosities.

Comparing the results of compressive strength and abrasion resistance of the studied granitic rocks with the standard specification relating to granite dimension stone51, it was found that all rock types achieved the minimum abrasion resistance limit (25 Ha). In the case of compressive strength, the rock types (F1, F2, F5, and F7) satisfied the requirements of compressive strength limit (131 MPa as a minimum limit), while the remaining rock types (F3, F4, and F6) were fallen slightly under the minimum requirement of the same specification, however, they can be adequate for the light duty purposes such as interior use and for the exterior use such as building cladding. Furthermore, they can be used provided that they are evaluated in terms of thermal expansion, durability, elastic modulus, and permanent volume change51. The summary of the engineering properties of the studied granitic rock types at Gabal El-Faliq area was presented in (Table 5).

The thermal expansion phenomenon occurs under increasing temperature in all substances and in all forms of matter. It also includes the contraction of matter upon decreasing temperature. During this phenomenon, the shape, length, and volume of the substance change with changing temperature67. Therefore, the increase in linear dimensions, such as the length, of any material with temperature can be used to quantify its thermal expansion68.

As early mentioned, the thermal expansion as a result of heat transfer, is one of the deteriorative reasons for the rocks. Therefore, due to the badly heat conductivity of granitic rocks, the thermal action on the rock surface is more intense than in its interior, and a tension force develops causing the formation of cracks in the outer surface of the rock23.

The numerical formulae for calculating the coefficient of linear thermal expansion can be grouped into two broad categories; the first one is "temperature range-dependent expansion", while the second is "single temperature—dependent expansion.

The first category is defined as "the average or the mean coefficient of linear thermal expansion (αm) over a temperature range68,69,70,71 according to the following general equation:

Where, αm is related to the slope of the chord between two points on the curve of length against temperature (Fig. 7)68,69, and so it represents the expansion over a particular temperature range from T1 to T2, Lo represents the initial specimen's length at temperature To (reference temperature) that expands to L1 at temperature T1 then to L2 at temperature T2, while ΔL is the change in specimen's length for the temperature change ΔT.

The second category is termed “true coefficient of linear thermal expansion (αT) that is related to the derivative (dL/dT) at a single temperature68,69, which can be defined according to the following equation:

Where, αT is the slope of the tangent to the curve of length against temperature as shown in (Fig. 10)68, dL/Lo is the derivative of thermal strain72. The results of the coefficient of linear thermal expansion (α) as well as the change in specimen's length as functions of temperature change for the studied intrusive granitic rock at Gebel El-Faliq area were graphically illustrated in (Fig. 10) and presented in Table 6.

(A) Change in material length (L) as a function of temperature (T) (James et al. 2001)68; (F1–F7) change in coefficient of linear thermal expansion (α) and thermal strain of different intrusive granitic rocks under rising temperatures.

Figure 10 shows the change in specimen's length (dL), as a function of thermal strain (dL/Lo, %), as well as the thermal coefficient (αm, αT) under the influence of the temperature increasing (T) up to 1000 °C. From this figure, it can observe an increase in the specimen's length with a gradual heating of the rocks over the all temperature range, while the thermal coefficient just increased up to (~573 °C) and returned to decrease over this temperature degree. There was a variation in the values of both change in specimen's length (dL) and mean thermal coefficient (αm) over the temperature range between the investigated rocks as given in (Table 6), such variation may be influenced by several parameters as follows:

As it was known that the intrusive igneous rocks are of multi-mineralogical composition and the main mineral composition is quartz and feldspar (two types) in addition to minor minerals in different proportions. At 100 °C, the increase in quartz content led to an increase in the specimen's length and expansion coefficient (Fig. 11a), while the increase in total feldspar content (Fig. 11b) and the combination of quartz and feldspar content (Fig. 11c) resulted in a reduction in the length of the specimens along with expansion coefficient. This is due to the high thermal coefficient value of quartz mineral (around 16.66 × 10−6/°C) relative to that of feldspar group (4.16 × 10−6/°C for plagioclase and 3.68 × 10−6/°C for alkali feldspar)67. As given in (Table 6), the minimum values of linear expansion along with expansion coefficient were recorded for (F2- Perthite-gneissose granites of medium-grained crystals) with (0.0021%) and (0.30 × 10-6/K−1), while the maximum values were recorded for (F3- Biotite-gneissose granites of fine-grained crystals) with (0.0385%) and (5.531 × 10-6 /K−1), respectively.

Linear Thermal Expansion (LTE) of Gabal El-Faliq granitic rocks as a function of mineralogical composition (quartz, feldspar content).

Correspondingly, the effect of quartz and total feldspar contents on the thermal behavior of the studied rocks at elevated temperatures demonstrated a similarity to that at lower temperatures. For example, at ~573 °C, the increase in quartz and feldspar content led to an increase and decrease in linear expansion and expansion coefficient (Fig. 11d–f), respectively.

As listed in (Table 6), the values of change in specimen length of the investigated rocks along with their thermal expansion coefficients up to (~573 °C) ranged from (1.2603%) and (23.009 × 10−6 / K-1) for (F7-Alkali-feldspar granite of a medium-grained size) to (2.0215 %) and (37.962 × 10−6 / K−1) for (F4- Alkali-feldspar granite of a coarse-grained size). Relating the thermal behavior of the investigated rocks, (up to ~573 °C), to their mineralogical composition, there was a positive relationship with quartz content (Fig. 11d), while a negative relationship with total feldspar content (Fig. 11e).

The influence of the mineralogical composition (Quartz and feldspar) of the studied granitic rocks on their thermal behavior was found similar to the findings reported by (Siegesmund et al. 201822, De Castro and Paraguass 200423).

Regarding the effect of higher temperatures, exceeding (~573 °C), on the thermal behavior of the studied rocks, a noticeable reduction in the thermal coefficient (αm) values was observed. This may be attributed to the phase transition of quartz mineral from (α to β) that appears at 573 °C7 and may influence the physical properties of rocks72. Such reduction seemed similar to the findings obtained by (Alzahrani et al. 2022)7. According to (Plevova et al. 2016)25 the rocks of high quartz content demonstrated a lower thermal expansion coefficient upon heating above ~ 573 °C (α-β quartz phase transition).

Regarding the thermal expansion coefficients at specific temperatures namely (true thermal expansion coefficient, αT), (Fig. 10) illustrates only one sharp peak (increase) for all studied granitic rocks at around 573 °C. The thermal coefficient values at this temperature ranged from (140 x 10−6 / K−1) for (F-1 Biotite-gneissose granites with medium-grained size) to (250 x 10−6 / K−1) for (F-4 Alkali-feldspar granites with coarse-grained size). Such variation in the αT values may be attributed to the variation in the amounts of quartz and feldspar minerals between the studied granitic rocks as presented in (Table 4). Figure 11f illustrates the relationship between quartz and feldspar content in the studied granitic rocks and the intensity of thermal. The sudden increase in the thermal expansion coefficient at around 573 °C may be related to the transitional state of quartz mineral from α-quartz to β quartz phase7,69.

Similar to the mineralogical composition, the intrusive granitic rocks are characterized by a high content of silicon oxide (SiO2) that ranges in this study from (72.417–76.225%) in addition to fluxing or alkali oxides (Na2O and K2O). In the present study, the relationship between the main chemical composition of the studied granitic rocks represented by (SiO2 and Na2O + K2O) and their thermal behavior at low and high temperatures was illustrated in (Fig. 12).

Linear Thermal Expansion (LTE) of Gabal El-Faliq granitic rocks as a function of chemical composition (SiO2, Na2O+K2O) and physical properties (apparent porosity, bulk density).

Regarding the effect of the chemical composition of the studied intrusive rocks on their expansion behavior, it was observed that the rock samples of high (SiO2, %) and (Na2O+K2O, %), achieved lower values of linear thermal expansion than that of lower contents at lower temperatures (100 °C) (Fig. 12a,b).

On the contrary, the effect of (SiO2, %) content on the thermal behavior of the studied rocks at elevated temperatures (~ 573 °C) was different, where there is a positive relationship between the SiO2 content of rock samples and their thermal expansion values (Fig. 12c).

Figure 12d–f illustrates the linear thermal expansion behavior of different types of granitic rocks at Gebel El-Faliq area as a function of their physical properties such as apparent porosity and bulk density. According to (Siegesmund et al. 2018)22, micro cracks can avoid or enhance mineral expansion depending on their size, density, and orientation, therefore, they could play an important role in the thermal expansion. According to (De Castro and Paraguass 2004)23 the increase in apparent porosity and grain size of minerals caused a decrease in the thermal expansion of some Brazilian granitic rocks.

In the present study it can observe a positive relationship between the apparent porosity of the granitic rocks and their thermal behavior at lower temperatures (up to 100 °C), while at higher temperatures (up to ~ 573 °C) a negative relationship is observed. On the contrary, a positive relationship can be noticed between the bulk density of the studied rocks and their linear thermal expansion at higher temperatures (up to ~ 573 °C).

The geotechnical assessment of any rock for use as dimension or ornamental stones in several building and structural purposes requires several geological and geotechnical studies. In the present study, the geological studies in terms of petrography, mineralogy, and geochemistry, along with the geotechnical measurements or engineering properties in terms of physical, mechanical, and thermal behaviors, were applied on different types of Neoproterozoic igneous rocks named "granite" on a commercial base, from Gebel El-Faliq area, Central Eastern Desert, Egypt for determining their suitability for using as dimension stones in different decorative purposes. The findings of geological and geotechnical studies were drawn as follows:

Based on the petrographic investigation, the studied intrusive rocks were classified into two main categories: gneissose granites (Biotite–Perthite) of medium- to fine-grained size and alkali-feldspar granites of coarse- to medium-grained size. Furthermore, some alteration minerals such as chlorite, saussurite, and sericite minerals were also petrographically detected.

The geochemical studies of the studied rock types revealed that the main mineral composition is albite, orthoclase and quartz in varying proportions, along with some accessory minerals such as apatite and rutile in addition to some minor quantities of iron-group minerals such as hematite and ilmenite.

The geotechnical measurements revealed that the maximum water absorption and apparent porosity values are 0.34% and 0.77%, respectively, while the minimum bulk density is 2604.03 kg/m3. The compressive strength results ranged from 999.68 to 2469.10 kg/cm2, while that of abrasion resistance varied from 29.67 to 54.64 Ha. Linking the petrographic analysis of rocks with their engineering performance, it is observed that the mineral composition has a remarkable effect on the physical and mechanical properties. The increase in albite content led to an increase in water absorption while a decrease in bulk density and compressive strength. This effect is reversed in case of orthoclase content. Furthermore, the increase in the grain size of rock leads to an increase in apparent porosity and decrease in compressive strength and abrasion resistance consequently.

The studied rock types exhibited great variations in their thermal expansion under changes in temperatures, mineral composition, and physical properties. The stepwise heating increased the thermal expansion coefficient until around 573 °C. The increase in quartz content led to an increase in expansion coefficient. On the contrary, the increase in feldspar content led to a decrease in the expansion coefficient. The increase in apparent porosity caused an increase in thermal expansion up to 100 °C, where the maximum change in rock length did not exceed 0.038%, which confirms the suitability of using the granitic rocks in outdoor decorative purposes (cladding/paving) under variable temperature conditions.

By comparing the results of the engineering properties with the limit of a standard specification related to dimension stones of granite, it was found that the requirements of the studied granitic rocks as a dimension stones were achieved.

Based on the obtained results, it is highly recommended to apply these types of granitic igneous rocks as building flooring for interior purposes of light duty or as building cladding for exterior use.

The sizes and orientations (direction) of the mineral crystals, in addition to the mineral alterations in the igneous rocks should be studied intensively. These parameters are considered important parameters that may have a considerable role in the properties of rocks under temperature variations and loads.

All data and materials availability statement is present within the text of the manuscript.

ASTM C119, 2014. Standard Terminology Relating to Dimension Stone, American society for testing and materials, West Conshohocken, PA, USA

Careddu, N. Dimension stones in the circular economy world. Resour. Policy 60, 243–245. https://doi.org/10.1016/j.resourpol.2019.01.012 (2019).

Article Google Scholar

Ciccu, R., Cosentino, R., Montani, C., El Kotb, A., Hamdy, H., 2005. Strategic study on the Egyptian Marble and Granite sector (Industrial Mdernization Centre Ref-PS1.

Gomes, V. R. et al. Ornamental stone wastes as an alternate raw material for soda-lime glass manufacturing. Mater. Lett. 269, 127579. https://doi.org/10.1016/j.matlet.2020.127579 (2020).

Article CAS Google Scholar

USGS, 2022. Geological Survey. www.usgs.gov/centers/national-minerals-informationcenter/dimension-stone-statistics-and-information.

Rana, A., Kalla, P., Verma, H. K. & Mohnot, J. K. Recycling of dimensional stone waste in concrete: A review. J. Clean. Prod. 135, 312–331. https://doi.org/10.1016/j.jclepro.2016.06.126 (2016).

Article Google Scholar

Alzahrani, A. M., Lasheen, E. S. R. & Rashwan, M. A. Relationship of mineralogical composition to thermal expansion, spectral reflectance, and physico-mechanical aspects of commercial ornamental granitic rocks. Materials 15, 2041. https://doi.org/10.3390/ma15062041 (2022).

Article ADS CAS PubMed Central PubMed Google Scholar

Ludovico-Marques, M., Chastre, C. & Vasconcelos, G. Modelling the compressive mechanical behaviour of granite and sandstone historical building stones. Constr. Build. Mater. 28, 372–381. https://doi.org/10.1016/j.conbuildmat.2011.08.083 (2012).

Article Google Scholar

ASTM C503/C503M, 2010. Standard Specification for Marble Dimension Stone, American society for testing and materials, West Conshohocken. PA, USA.

Ericsson, M. XXIX world marble and stones report 2018 by Carlo Montani: Aldus Casa di Edizioni, Carrara Italy 2018 E-mail: [email protected]. Miner. Econ. 32, 255–256. https://doi.org/10.1007/s13563-019-00183-6 (2019).

Article Google Scholar

Singh Chouhan, H., Kalla, P., Nagar, R. & Kumar Gautam, P. Influence of dimensional stone waste on mechanical and durability properties of mortar: A review. Constr. Build. Mater. 227, 116662. https://doi.org/10.1016/j.conbuildmat.2019.08.043 (2019).

Article CAS Google Scholar

Sadek, D. M., El-Attar, M. M. & Ali, H. A. Reusing of marble and granite powders in self-compacting concrete for sustainable development. J. Clean. Prod. 121, 19–32. https://doi.org/10.1016/j.jclepro.2016.02.044 (2016).

Article Google Scholar

Rashwan, M. A. & Abdel-Shakour, Z. A. Low-cost, highly-performance fired clay bodies incorporating natural stone sludge: Microstructure and engineering properties. Clean Waste Syst. https://doi.org/10.1016/j.clwas.2022.100041 (2022).

Article Google Scholar

Mashaly, A. O., El-Kaliouby, B. A., Shalaby, B. N., El-Gohary, A. M. & Rashwan, M. A. Effects of marble sludge incorporation on the properties of cement composites and concrete paving blocks. J. Clean. Prod. 112, 731–741. https://doi.org/10.1016/j.jclepro.2015.07.023 (2016).

Article Google Scholar

Lasheen, E. S. R. et al. Radiological hazards and natural radionuclide distribution in granitic rocks of Homrit Waggat Area, Central Eastern Desert, Egypt. Materials 15, 4069. https://doi.org/10.3390/ma15124069 (2022).

Article ADS CAS PubMed Central PubMed Google Scholar

Lasheen, E. S. R., Mohamed, W. H., Ene, A., Awad, H. A. & Azer, M. K. Implementation of petrographical and aeromagnetic data to determine depth and structural trend of Homrit Waggat Area, Central Eastern Desert, Egypt. Appl. Sci. 12, 8782. https://doi.org/10.3390/app12178782 (2022).

Article CAS Google Scholar

Lasheen, E. S. R., Saleh, G. M., Khaleal, F. M. & Alwetaishi, M. Petrogenesis of neoproterozoic ultramafic rocks, Wadi Ibib-Wadi Shani, South Eastern Desert, Egypt: Constraints from whole rock and mineral chemistry. Appl. Sci. 11, 10524. https://doi.org/10.3390/app112210524 (2021).

Article CAS Google Scholar

Lasheen, E. S. R. et al. Radiological hazard evaluation of some Egyptian magmatic rocks used as ornamental stone: Petrography and natural radioactivity. Materials 14, 7290. https://doi.org/10.3390/ma14237290 (2021).

Article ADS CAS PubMed Central PubMed Google Scholar

Azer, M. K., Abdelfadil, K. M., Asimow, P. D. & Khalil, A. E. Tracking the transition from subduction-related to post-collisional magmatism in the north Arabian-Nubian Shield: A case study from the Homrit Waggat area of the Eastern Desert of Egypt. Geol. J. 55, 4426–4452. https://doi.org/10.1002/gj.3643 (2020).

Article CAS Google Scholar

Seddik, A. M. A., Darwish, M. H., Azer, M. K. & Asimow, P. D. Assessment of magmatic versus post-magmatic processes in the Mueilha rare-metal granite, Eastern Desert of Egypt, Arabian-Nubian Shield. Lithos 366–367, 105542. https://doi.org/10.1016/j.lithos.2020.105542 (2020).

Article CAS Google Scholar

Sami, M., El Monsef, M. A., Abart, R., Toksoy-Köksal, F. & Abdelfadil, K. M. Unraveling the genesis of highly fractionated rare-metal granites in the nubian shield via the rare-earth elements tetrad effect, Sr–Nd isotope systematics, and mineral chemistry. ACS Earth Space Chem. https://doi.org/10.1021/acsearthspacechem.2c00125 (2022).

Article Google Scholar

Siegesmund, S., Sousa, L. & Knell, C. Thermal expansion of granitoids. Environ. Earth Sci. 77, 41. https://doi.org/10.1007/s12665-017-7119-2 (2018).

Article ADS CAS Google Scholar

de Castro, J., Lima, J. & Paraguass, A. Linear thermal expansion of granitic rocks: Influence of apparent porosity, grain size and quartz content. Bull. Eng. Geol. Environ. https://doi.org/10.1007/s10064-004-0233-x (2004).

Article Google Scholar

Ramana, Y. V. & Sarma, L. P. Thermal expansion of a few Indian granitic rocks. Phys. Earth Planet. Inter. 22, 36–41. https://doi.org/10.1016/0031-9201(80)90098-9 (1980).

Article ADS Google Scholar

Plevova, E., Vaculikova, L., Kozusnikova, A., Ritz, M. & Martynkova, G. S. Thermal expansion behaviour of granites. J. Therm. Anal. Calorim. 123, 1555–1562 (2016).

Article CAS Google Scholar

Yusofa, N. Q. A. M. & Zabidia, H. Correlation of mineralogical and textural characteristics with engineering properties of granitic rock from Hulu Langat, Selangor. Proc. Chem. 19, 975–980. https://doi.org/10.1016/j.proche.2016.03.144 (2016).

Article Google Scholar

Eroğlu, G. & Çalik, A. Relationship of petrographic and mineralogical characteristics with mechanical strengthproperties of granitic rocks: A case study from the Biga Peninsula, NW Turkey. Turkish J. Earth Sci. 32, 126–143. https://doi.org/10.55730/1300-0985.1831 (2023).

Article CAS Google Scholar

Abd El–Hamid M.A., Draz W.M., Ismael AF, Gouda MA, Sleem S.M.,. Effect of petrographical characteristics on the engineering properties of some egyptian ornamental stones. Int. J. Sci. Eng. Res. 6(7), 116 (2015).

Google Scholar

Hemmati, A., Ghafoori, M., Moomivand, H. & Lashkaripour, G. R. The effect of mineralogy and textural characteristics on the strength of crystalline igneous rocks using image-based textural quantification. Eng. Geol. 266, 105467. https://doi.org/10.1016/j.enggeo.2019.105467 (2020).

Article Google Scholar

Rigopoulos, I., Tsikouras, B., Pomonis, P. & Hatzipanagiotou, K. The impact of petrographic characteristics on the engineering properties of ultrabasic rocks from northern and central Greece. Q. J. Eng. Geol. Hydrogeol. 45, 423–433. https://doi.org/10.1144/qjegh2012-021 (2012).

Article Google Scholar

Ribeiro, R. P., Paraguassú, A. B. & Rodrigues, J. E. Sawing of blocks of siliceous dimension stone: Influence of texture and mineralogy. Bull. Eng. Geol. Environ. 66, 101–107. https://doi.org/10.1007/s10064-006-0049-y (2007).

Article CAS Google Scholar

Rashwan, M. A., Lasheen, E. S. R. & Azer, M. K. Thermal and physico-mechanical evaluation of some magmatic rocks at Homrit Waggat Area, Eastern Desert, Egypt: Petrography and geochemistry. Bull. Eng. Geol. Environ. 82, 199. https://doi.org/10.1007/s10064-023-03208-1 (2023).

Article Google Scholar

Vigroux, M. et al. High temperature behaviour of various natural building stones. Constr. Build. Mater. 272, 121629. https://doi.org/10.1016/j.conbuildmat.2020.121629 (2021).

Article CAS Google Scholar

Petrounias, P. et al. The effect of petrographic characteristics and physico-mechanical properties of aggregates on the quality of concrete. Minerals 8, 577. https://doi.org/10.3390/min8120577 (2018).

Article ADS CAS Google Scholar

Petrounias, P. et al. The influence of alteration of aggregates on the quality of the concrete: A case study from serpentinites and andesites from central Macedonia (North Greece). Geosciences 8, 115. https://doi.org/10.3390/geosciences8040115 (2018).

Article ADS CAS Google Scholar

Kamar, M. S. et al. Contribution to the geological, geochemical and mineralogical studies of gabal serbal granitic rocks, Southwestern Sinai, Egypt. Int. J. Min. Sci. https://doi.org/10.20431/2454-9460.0701004 (2021).

Article Google Scholar

Hamdy, M. M., Lasheen, E. S. R. & Abdelwahab, W. Gold-bearing listwaenites in ophiolitic ultramafics from the Eastern Desert of Egypt: Subduction zone-related alteration of Neoproterozoic mantle?. J. Afr. Earth Sci. https://doi.org/10.1016/j.jafrearsci.2022.104574 (2022).

Article Google Scholar

Khaleal, F. M., Saleh, G. M., Lasheen, E. S. R., Alzahrani, A. M. & Kamh, S. Z. Exploration and petrogenesis of corundum-bearing pegmatites: A case study in Migif-Hafafit area, Egypt. Front. Earth Sci. 10, 869828. https://doi.org/10.3389/feart.2022.869828 (2022).

Article Google Scholar

Khaleal, F. M., Saleh, G. M., Lasheen, E. S. R. & Lentz, D. R. Occurrences and genesis of emerald and others beryl mineralization in Egypt: A review. Phys. Chem. Earth Parts ABC https://doi.org/10.1016/j.pce.2022.103266 (2022).

Article Google Scholar

Saleh, G. M., Khaleal, F. M. & Lasheen, E. S. R. Geochemistry and paleoweathering of metasediments and pyrite-bearing quartzite during the Neoproterozoic Era, Wadi Ibib-Wadi Suwawrib, South Eastern Desert. Egypt. Arab. J. Geosci. 15, 51. https://doi.org/10.1007/s12517-021-09141-5 (2022).

Article CAS Google Scholar

Saleh, G. M., Khaleal, F. M. & Lasheen, E. S. R. Petrogenesis of ilmenite-bearing mafic intrusions: A case study of Abu Ghalaga area, South Eastern Desert. Egypt. Arab. J. Geosci. 15, 1508. https://doi.org/10.1007/s12517-022-10782-3 (2022).

Article Google Scholar

Rashwan, M. A., Lasheen, E. S. R. & Shalaby, B. N. Incorporation of metagabbro as cement replacement in cement-based materials: A role of mafic minerals on the physico-mechanical and durability properties. Constr. Build. Mater. https://doi.org/10.1016/j.conbuildmat.2019.03.191 (2019).

Article Google Scholar

Rashwan, M. A., Lasheen, E. S. R. & Hegazy, A. A. Tracking the pozzolanic activity of mafic rock powder on durability performance of cement pastes under adverse conditions: Physicomechanical properties, mineralogy, microstructure, and heat of hydration. J. Build. Eng. 71, 106485. https://doi.org/10.1016/j.jobe.2023.106485 (2023).

Article Google Scholar

Mahmoud, S. A. E. A. Geology, mineralogy and mineral chemistry of the NYF-type pegmatites at the Gabal El Faliq area, South Eastern Desert. Egypt. J. Earth Syst. Sci. 128, 156. https://doi.org/10.1007/s12040-019-1169-7 (2019).

Article ADS CAS Google Scholar

Saleh, G. M., Salem, I. A., Darwish, M. E. & Mostafa, D. A. Gabal El Faliq granitoid rocks of the southeastern Desert, Egypt: Geochemicalconstraints, mineralization and spectrometric prospecting. World J. Earth Planet. Sci. 1, 1–22 (2014).

Google Scholar

Abou-ali, H., Elayouty, A., Mohieldin M., 2023. keys to climate action chapter 3: climate action in Egypt—challenges and opportunities. Center for Sustainable Development. https://www.brookings.edu/research/climate-action-in-egypt-challenges-and-opportunities/.

Eid, M. M., Gad, E. H. & Abdel Basset, H. Temperature analysis over Egypt. Al-Azhar Bull. Sci. 30(2), 13–30. https://doi.org/10.21608/absb.2019.86755 (2019).

Article Google Scholar

Nashwan, M. S. & Shahid, S. Future precipitation changes in Egypt under the 1.5 and 2.0 °C global warming goals using CMIP6 multimodel ensemble. Atmos. Res. 265, 105908. https://doi.org/10.1016/j.atmosres.2021.105908 (2022).

Article Google Scholar

Markus, K., Jürgen, G., Christoph, B., Bruno, R. & Franz, R. A world map of the Köppen-Geiger climate classification updated. Meteorologische Zeitschrift 15(3), 259–263. https://doi.org/10.1127/0941-2948/2006/0130 (2006).

Article Google Scholar

Streckeisen, A. To each plutonic rock its proper name. Earth-Sci. Rev. 12, 1–33. https://doi.org/10.1016/0012-8252(76)90052-0 (1976).

Article ADS CAS Google Scholar

ASTM C615/C615M, 2011. Standard Specification for Granite Dimension Stone, American society for testing and materials, West Conshohocken, PA, USA

ASTM C97/C97M, 2015. Standard Test Method for Absorption and Bulk Specific Gravity of Dimension Stone, American society for testing and materials, West Conshohocken, PA, USA

ASTM C170/C170M, 2015. Standard Test Method for Compressive Strength of Dimension Stone, American society for testing and materials, West Conshohocken, PA, USA

ASTM C 241, 2015. Standard Test Method for Abrasion Resistance of Stone Subjected to Foot Traffic, Annual Book of ASTM Standards, West Conshohocken, PA, USA.

De la Roche, H., Leterrier, J., Grandclaude, P. & Marchal, M. A classification of volcanic and plutonic rocks using R 1 R 2 -diagram and major-element analyses—Its relationships with current nomenclature. Chem. Geol. 29, 183–210. https://doi.org/10.1016/0009-2541(80)90020-0 (1980).

Article ADS Google Scholar

Irvine, T. N. & Baragar, W. R. A. A guide to the chemical classification of the common volcanic rocks. Can. J. Earth Sci. 8, 523–548. https://doi.org/10.1139/e71-055 (1971).

Article ADS CAS Google Scholar

Shand, S. J. Eruptive Rocks 4th edn. (John-Wiley, 1951).

Google Scholar

Sun, S. & McDonough, W. F. Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes. Geol. Soc. Lond. Spec. Publ. 42, 313–345. https://doi.org/10.1144/GSL.SP.1989.042.01.19 (1989).

Article ADS Google Scholar

Whalen, J. B., Currie, K. L. & Chappell, B. W. A-type granites: Geochemical characteristics, discrimination and petrogenesis. Contrib. Mineral. Petrol. 95, 407–419. https://doi.org/10.1007/BF00402202 (1987).

Article ADS CAS Google Scholar

Pearce, J. A., Harris, N. B. W. & Tindle, A. G. Trace element discrimination diagrams for the tectonic interpretation of granitic rocks. J. Petrol. 25, 956–983. https://doi.org/10.1093/petrology/25.4.956 (1984).

Article ADS CAS Google Scholar

Sylvester, P. J. Post-collisional alkaline granites. J. Geol. 97, 261–280 (1989).

Article ADS CAS Google Scholar

Laurent, O., Martin, H., Moyen, J. F. & Doucelance, R. The diversity and evolution of late-Archean granitoids: Evidence for the onset of “modern-style” plate tectonics between 3.0 and 2.5Ga. Lithos 205, 208–235. https://doi.org/10.1016/j.lithos.2014.06.012 (2014).

Article ADS CAS Google Scholar

Hatch, F. H., Wells, A. K. & Wells, M. K. The Petrology of the Igneous Rocks 10th edn. (Thomas Murby & Co, 1949).

Google Scholar

Török, A. & Török, Á. The effect of temperature on the strength of two different granites. Cent. Eur. Geol. 58, 356–369. https://doi.org/10.1556/24.58.2015.4.5 (2015).

Article Google Scholar

Freire-Lista, D. M., Gonçalves, G. V. & Vazquez, P. Weathering detection of granite from three asynchronous historical quarries of Sabrosa municipally (North Portugal). J. Cultural Heritage 58, 199–208. https://doi.org/10.1016/j.culher.2022.10.008 (2022).

Article Google Scholar

Dionísio, A., Martinho, E., Pozo-António, J. S., Sequeira Braga, M. A. & Mendes, M. Evaluation of combined effects of real-fire and natural environment in a building granite. Constr. Build. Mater. 277, 122327. https://doi.org/10.1016/j.conbuildmat.2021.122327 (2021).

Article CAS Google Scholar

Huotari, T., Kukkonen, L., 2004. Thermal fxpansion Properties of Rocks: literature Survey and fstimation of Thermal fxpansion Coefficient for Olkiluoto Mica Gneiss.

James, J. D., Spittle, J. A., Brown, S. G. R. & Evans, R. W. A review of measurement techniques for the thermal expansion coefficient of metals and alloys at elevated temperatures. Meas. Sci. Technol. 12, R1–R15. https://doi.org/10.1088/0957-0233/12/3/201 (2001).

Article ADS CAS Google Scholar

Wang, F., Konietzky, H., Frühwirt, T. & Dai, Y. Laboratory testing and numerical simulation of properties and thermal-induced cracking of Eibenstock granite at elevated temperatures. Acta Geotech. 15, 2259–2275. https://doi.org/10.1007/s11440-020-00926-8 (2020).

Article Google Scholar

ASTM E 228, 2017. Standard Test Method for Linear Thermal Expansion of Solid Materials With a Push-Rod Dilatometer, Annual Book of ASTM Standards, West Conshohocken, PA, USA.

ASTM E 289, 2017. Standard Test Method for Linear Thermal Expansion of Rigid Solids with Interferometry, Annual Book of ASTM Standards, Pennsylvania, USA.

Gautam, P. K., Verma, A. K., Singh, T. N., Hu, W. & Singh, K. H. Experimental investigations on the thermal properties of Jalore granitic rocks for nuclear waste repository. Thermochim. Acta 681, 178381. https://doi.org/10.1016/j.tca.2019.178381 (2019).

Article CAS Google Scholar

Download references

The authors greatly appreciate all efforts offered by “Marble and Granite Test Lab” (MGTL) at National Research Centre (NRC) including physical and mechanical measurements of the collected rock samples. Special thanks to Professor Basel Shalaby at the National Research Centre for reviewing and editing the manuscript. Thanks to X-Ray Testing Lab (XRF) for the chemical analysis of the stone samples.

Open access funding provided by The Science, Technology & Innovation Funding Authority (STDF) in cooperation with The Egyptian Knowledge Bank (EKB). The authors declare that no funds, grants, or other support were received during the preparation of this manuscript.

Geology Department, Faculty of Science, Al-Azhar University, P.O. 11884, Cairo, Egypt

El Saeed R. Lasheen

Geological Sciences Department, National Research Centre, 33 El Bohooth st. (former El Tahrir st), Dokki, P.O. 12622, Giza, Egypt

Mohammed A. Rashwan & Mokhles K. Azer

You can also search for this author in PubMed Google Scholar

You can also search for this author in PubMed Google Scholar

You can also search for this author in PubMed Google Scholar

The study was conceptualized and designed by [M.A.R.]. The samples were collected by [M.K.A.] and were prepared and analyzed by [M.A.R.] and [E.S.R.L.]. The first draft of the manuscript was written by [M.A.R.] and [E.S.R.L.] and all authors commented on previous versions of the manuscript. The physical, mechanical, and thermal properties were investigated by [M.A.R.], while the petrographic and geochemical investigations were performed by [E.S.R.L.]. All authors read and approved the final manuscript. All authors are agreed for publication of this manuscript in the Scientific Reports journal.

Correspondence to Mohammed A. Rashwan.

The authors declare no competing interests.

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

Reprints and Permissions

Lasheen, E.S.R., Rashwan, M.A. & Azer, M.K. Effect of mineralogical variations on physico-mechanical and thermal properties of granitic rocks. Sci Rep 13, 10320 (2023). https://doi.org/10.1038/s41598-023-36459-9

Download citation

Received: 07 September 2022

Accepted: 04 June 2023

Published: 26 June 2023

DOI: https://doi.org/10.1038/s41598-023-36459-9

Anyone you share the following link with will be able to read this content:

Sorry, a shareable link is not currently available for this article.

Provided by the Springer Nature SharedIt content-sharing initiative

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.